The photos, taken by her mother the Duchess of Cambridge, were taken in April at the their family home, Anmer Hall in Norfolk.
Princess Charlotte, who turns one on Monday, is pictured walking for the first time, with the help of a baby walker.
Kensington Palace said the Duke and Duchess of Cambridge were “delighted” to release the pictures.
The Palace said in a statement: “The duke and duchess are very happy to be able to share these important family moments and hope that everyone enjoys these lovely photos as much as they do."