( ) (, , - / , )T. =T. +*n. -/m=(T. -T. )*m*M. -/m. -==(80,714-80,2)º*0,1*152//3,04=2,57 º*/. FeSO4, Na2CO3, KCl ? ? - 1- . pH (>7< ) ?KCl - , , =7FeSO4 (II) , , <7Fe2++ HOH = FeOH++ H+2FeSO4+ HOH = (FeOH)2SO4+ H2SO4Na2CO3 , , >7CO32-+ HOH = HCO3-+ OH-Na2CO3+ HOH = NaHCO3+ NaOH. , Ca2+- 0.110 /; Mg2+- 0.0425 /; HCO3-- 0.07/ ? , .. C(Ca2+)=0,110//40,08/=0,00274 /=2,74 /C(Mg2+)=0,0425//24,3/=0,00175 /=1,75 /C(HCO3-)=0,07//61,02/=0,00115 /=1,15 / - C(Ca2+)+C(Mg2+)=4,49 / - ( -)C(Ca(HCO3)2)+C(Mg(HCO3)2)=0.5*C(HCO3-)=0.57 / Ca2++ 2HCO3-→ CaCO3↓ + CO2↑ + H2OMg2++ 2HCO3-→ MgCO3↓ + CO2↑ + H2O Ca(HCO3)2→ CaCO3↓ + CO2↑ + H2OMg(HCO3)2→ MgCO3↓ + CO2↑ + H2O - (, )C(Ca2+)+C(Mg2+)-(C(Ca(HCO3)2)+C(Mg(HCO3)2))=C(Ca2+)+C(Mg2+)-0.5*C(HCO3-)=3,92 /. ( ): NaNO3; SnCl2. ? , 2 100 .. NaNO3 : 2H2O + 2ē = H2+ 2OH-(NaOH) 2H2O 4 ē = O2+ 4 H+(HNO3) NaNO3 = 7 Na+, NO3-, H+ -. Na+(E0= -2,714 ) , +(0= 0,41 ), NO3-(0=-0,12 ) , -(0= +0,82 ), , , .. . , Na+ , NO3- , , 2. Sn2+ Cl-. Sn2+ , Cl . , Sn2+(0 = -0,133 ), , () . , . , , , Sn2+ . (0= 1,359 ), Cl- , = 7 2H2O + 2ē = H2+ 2OH- 2Cl-- 2ē = Cl23. 2H2O + 2ē = H2+ 2OH-(KOH) , m = I*t*M/F m ();I ();t (); (/);F (96500 /). 56 /2 2*60*60= 7200 m= 100*7200*56/96500 = 417,82 .. . , , .) T=298 K;) , ..) 4Al + 3O2= 2Al2O3) ( ), .0(Fe2+/Fe) = -0,44 B;0(Sn2+/Sn) = -0,133 B. , , - , - ()Fe /HCl /Sn (K)(A) - Fe - 2ē = Fe2+(K) - 2H++ 2ē = H2 Fe + 2H+= Fe2++ H2 Fe + 2HCl = FeCl2+ H2.